Chemistry · real student question

A reaction between 2.0 g of silver nitrate and 3.0 g of sodium chloride yields how many grams of the precipitate silver chloride?

Question

A reaction between 2.0 g2.0\ \text{g} of silver nitrate and 3.0 g3.0\ \text{g} of sodium chloride yields how many grams of the precipitate silver chloride?

Step-by-step solution

  1. Write and balance the equation first. Stoichiometry is meaningless without the mole ratio, and here the ratio is what makes the arithmetic simple:

    AgNO3+NaClAgCl+NaNO3\mathrm{AgNO_3} + \mathrm{NaCl} \rightarrow \mathrm{AgCl}\downarrow + \mathrm{NaNO_3}

    The equation is already balanced, so silver nitrate, sodium chloride and silver chloride are all in a 1:1:11:1:1 ratio.

  2. Compute the molar masses needed. Using Ag=107.87\mathrm{Ag}=107.87, N=14.01\mathrm{N}=14.01, O=16.00\mathrm{O}=16.00, Na=22.99\mathrm{Na}=22.99, Cl=35.45 g/mol\mathrm{Cl}=35.45\ \text{g/mol}:

    M(AgNO3)=169.88,M(NaCl)=58.44,M(AgCl)=143.32 g/molM(\mathrm{AgNO_3}) = 169.88, \quad M(\mathrm{NaCl}) = 58.44, \quad M(\mathrm{AgCl}) = 143.32\ \text{g/mol}

  3. Convert both reactant masses to moles. Grams cannot be compared directly — only moles can, because the balanced equation counts particles, not mass:

    n(AgNO3)=2.0169.88=0.01177 mol,n(NaCl)=3.058.44=0.05133 moln(\mathrm{AgNO_3}) = \frac{2.0}{169.88} = 0.01177\ \text{mol}, \qquad n(\mathrm{NaCl}) = \frac{3.0}{58.44} = 0.05133\ \text{mol}

  4. Identify the limiting reactant. With a 1:11:1 requirement, whichever reactant supplies fewer moles runs out first. Silver nitrate offers only 0.01177 mol0.01177\ \text{mol} against 0.05133 mol0.05133\ \text{mol} of sodium chloride, so AgNO3\mathrm{AgNO_3} is limiting and sodium chloride is in large excess — despite weighing more on the balance, because its molar mass is roughly three times smaller.

  5. Convert limiting moles to moles, then grams, of product. The 1:11:1 ratio carries the moles straight across, and the molar mass converts back to a mass:

    n(AgCl)=0.01177 molm=0.01177×143.32=1.687 gn(\mathrm{AgCl}) = 0.01177\ \text{mol} \quad\Longrightarrow\quad m = 0.01177 \times 143.32 = 1.687\ \text{g}

  6. Round sensibly and check. The data carry two significant figures, so report 1.69 g1.69\ \text{g} (about 1.7 g1.7\ \text{g}) of AgCl\mathrm{AgCl}. Mass balance confirms the result: the products are 1.69 g1.69\ \text{g} of AgCl\mathrm{AgCl} plus 1.00 g1.00\ \text{g} of dissolved NaNO3\mathrm{NaNO_3}, and 2.31 g2.31\ \text{g} of sodium chloride is left over unreacted — a total of 5.0 g5.0\ \text{g}, exactly the mass put in.

Answer

m(AgCl)1.69 gm(\mathrm{AgCl}) \approx 1.69\ \text{g}

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